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Tuesday, April 22, 2025

Decay

Smoke detectors are fascinating. They contain a tiny radioactive sample of Americium-241, the atoms of which are continuously decaying into Neptunium-237. Alpha decay is when the nucleus of an atom emits an alpha particle, which is made of 2 protons and 2 neutrons. The half-life of Am is approximately 432.2 years, which means that if you start off with N0 atoms at t=0 then at t=1 you'll have 12N0 and at t=2 you'll have 14N0 left. Generally:

Nt=N0(12)t

This is an exponential function, so if you wanted to, you could rewrite it as:

Nt=N0etln12

ln12 is an interesting constant that will reappear later. It's roughly equivalent to 0.69314718.

If you plotted the above graph, you might note that time is on the x-axis and the number of Am atoms is on the y-axis. This number is always decreasing as time increases. For a given time interval t=a,t=b, the decrease in N from Na to Nb is a direct consequence of the activity. 

Activity, measured in Becquerels Bq, is the number of decays per second, but as our graph's time axis is currently measured in half-lives we can't just read the activity directly from the slope. 

Approach #1

432.2years×365.25×24×3600=13639194720secs

If we already had N0 we could plug 113639194720 into our first equation and see N one second later. This would be the number of Becquerels.

Approach #2

Modify the original equation so that t is no longer measured in half-lives but instead in seconds:

Nt=N0(12)t13639194720

So actually, both approaches are identical, but the second approach is more reusable: we've taken the general equation 1 and altered it to be specific to the half-life of Americium-241. 

Let's find a typical value of N0 for our smoke detector example, where a Google search reveals about 0.3μg is common. How do we find the number of Americium-241 atoms in 0.3μg? Avogadro's number: 6.02214076×1023 is the number of particles in one mole.

N0=0.3×106/241×6.02214076×1023=7.49644×1014

Let's plug this number into equation 4. Unsurprisingly, if you follow along in Excel, you'll see the same number for N0 as N1.

N1=7.49644×1014

However, if you rearrange it, you'll find that Excel didn't throw away the bits, it just hid them away with some formatting that prioritises the most significant digits:

N0N1=38097.125

Here you have it. In a smoke detector with just 0.3μg of Americium 241, there are approximately 38k decays per second. Alpha particles are being emitted at 38kHz! Note that in equation 7, N1N0 would give us a negative slope of 38097.125 indicating that our sample contained fewer atoms at t=1.

Bonus section:

The slope of the exponential function 1 is always directly proportional to the value on the y-axis! In this case, the N value is scaled by ln12 while exponential function 4 is scaled by a different number ln1213639194720. Intuitively this should make sense: when the amount of radioactive material is halved, so is the activity.