Smoke detectors are fascinating. They contain a tiny radioactive sample of Americium-241, the atoms of which are continuously decaying into Neptunium-237. Alpha decay is when the nucleus of an atom emits an alpha particle, which is made of 2 protons and 2 neutrons. The half-life of Am is approximately 432.2 years, which means that if you start off with N0 atoms at t=0 then at t=1 you'll have 12N0 and at t=2 you'll have 14N0 left. Generally:
Nt=N0(12)t
This is an exponential function, so if you wanted to, you could rewrite it as:
Nt=N0etln12
ln12 is an interesting constant that will reappear later. It's roughly equivalent to −0.69314718.
If you plotted the above graph, you might note that time is on the x-axis and the number of Am atoms is on the y-axis. This number is always decreasing as time increases. For a given time interval t=a,t=b, the decrease in N from Na to Nb is a direct consequence of the activity.
Activity, measured in Becquerels Bq, is the number of decays per second, but as our graph's time axis is currently measured in half-lives we can't just read the activity directly from the slope.
Approach #1
432.2years×365.25×24×3600=13639194720secs
If we already had N0 we could plug 113639194720 into our first equation and see N one second later. This would be the number of Becquerels.
Approach #2
Modify the original equation so that t is no longer measured in half-lives but instead in seconds:
Nt=N0(12)t13639194720
So actually, both approaches are identical, but the second approach is more reusable: we've taken the general equation 1 and altered it to be specific to the half-life of Americium-241.
Let's find a typical value of N0 for our smoke detector example, where a Google search reveals about 0.3μg is common. How do we find the number of Americium-241 atoms in 0.3μg? Avogadro's number: 6.02214076×1023 is the number of particles in one mole.
N0=0.3×10−6/241×6.02214076×1023=7.49644×1014
Let's plug this number into equation 4. Unsurprisingly, if you follow along in Excel, you'll see the same number for N0 as N1.
N1=7.49644×1014
However, if you rearrange it, you'll find that Excel didn't throw away the bits, it just hid them away with some formatting that prioritises the most significant digits:
N0−N1=38097.125
Here you have it. In a smoke detector with just 0.3μg of Americium 241, there are approximately 38k decays per second. Alpha particles are being emitted at 38kHz! Note that in equation 7, N1−N0 would give us a negative slope of −38097.125 indicating that our sample contained fewer atoms at t=1.